carbanide, chloropalladium (1+), (1Z, 5Z) -cycloocta-1,5-diene CAS: 63936-85-6

Lub Palladium (II) Chloro complex [(C8H12)(Cl)Pd] yog tsim los ntawm kev sib koom tes ntawm PdCl4 thiab trans-(1R,5S)-cycloocta-1,5-diene molecules los ntawm dative bonds. Cov khoom tsim muaj ib qho dienyl ligand khi rau txhua lub chaw hlau plaub ntawm eta-coordination. Lub complex no muaj kev ruaj khov thermal siab vim muaj zog intermolecular hauv cov qauv. Nws daim ntawv thov yog nyob rau hauv cov txheej txheem catalytic uas cuam tshuam nrog kev sib txuas sib txuas. Piv txwv li, hom tsiaj no pab txhawb kev tsim C-C bond thaum lub sijhawm Suzuki Coupling Reaction uas cuam tshuam nrog kev koom ua ke sp2 hybridized carbon atoms ua ke siv boronic acids ua nucleophiles. Cov nyiaj tshiab tsim tawm txhim kho cov khoom siv ntawm cov khoom siv hauv cov khoom siv hluav taws xob yog li ua rau lawv ua haujlwm tau zoo dua. Ntxiv mus, cov catalyst no pom daim ntawv thov hauv Sonogashira coupling reaction qhov twg sp hybridized atoms raug txuas ua ke siv cov davhlau ya nyob twg alkynes ua rau kev tsim ntawm C-C bond yog li tsim cov pab pawg ua haujlwm tshiab uas muaj peev xwm siv tau hauv ntau qhov chaw suav nrog kev tsim tshuaj thiab kev tshawb fawb txog khoom siv.